| 학회 |
한국고분자학회 |
| 학술대회 |
2010년 가을 (10/07 ~ 10/08, 대구 EXCO) |
| 권호 |
35권 2호 |
| 발표분야 |
고분자 합성 |
| 제목 |
SYNTHESIS OF MULTI HYDROXYL GROUPS SUPPORTED CATALYSTS BEARING Ni(II) α-DIIMINE COMPLEXES FOR ETHYLENE POLYMERIZATIONS |
| 초록 |
A series of highly active multi-hydroxy supported ethylene polymerization catalysts based on bidentate α-diimine ligands coordinated to Ni(II) have been successfully synthesized and characterized. The supported catalysts show high activities in presence of various alkylaluminium co-catalysts such as ethylaluminium sesqichloride (EASC) and methylaluminoxane (MAO). Polymerization activity of all catalysts was investigated under atmospheric and high pressure conditions at various temperatures. Among the co-catalysts, EASC records the best activity. The thermal stability of the catalysts was enhanced to a greater extent by heterogeneous support, and the resulting polyethylenes show uniform morphology. |
| 저자 |
렌지스1, 하창식2, 김일1
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| 소속 |
1부산대, 2합성고분자 생물접합 하이브리드 재료사업단 |
| 키워드 |
: Ni(II) complexes; heterogeneous catalyst; multihydroxyl groups; polyethylene
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| E-Mail |
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