화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2011년 봄 (04/07 ~ 04/08, 대전컨벤션센터)
권호 36권 1호
발표분야 고분자가공/복합재료
제목 Triblock Copolymer Synthesis of Highly Ordered Mesoporous Silica for Multifunctional Fluorescent Sensor in Chemical and Biological Probing
초록 A versatile solid-state fluorescent sensor has been designed by functionalizing large-pore mesoporous silica templated by triblock copolymer with 3-isocyanatopropyltriethoxysilane and dansylcadaverine. The functionalized mesoporous silica material exhibited highly selective Hg2+ sensing due to the fluorophore moiety grafted on its surface. Much interestingly, the Hg2+-bound mesoporous material was able to be utilized in detecting various amino acids (especially highly sensitive to phenylalanine acid) in aqueous solution. More importantly, the dansylcadaverine-functionalized large-pore mesoporous material could be applied to fluorescent turn-on sensing of bovine serum albumin, demonstrating an all-round smart sensor in chemical and biological application.
저자 구완핑, 왕정, 하창식
소속 부산대
키워드 triblock copolymer; mesoporous silica; sensor
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