화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2005년 봄 (05/13 ~ 05/14, 충남대학교)
권호 9권 1호
발표분야 환경,에너지
제목 Isoprene/n-pentane separation using sulfonated ionomer membranes containing SPEEK-AgNO3
초록 The separation of olefin from hydrocarbon mixtures is an important part of petrochemical industry. Since conventional cryogenic distillation processes for the separation of olefin/paraffin are energy-intensive, an alternative energy saving process is requiring. Among a number of alternative technologies, separation using facilitated transport membrane with metal ion such as Cu+ or Ag+ was attracted much interest because of its low energy consumption process. Sulfonated ionomer membranes, sulfonated poly(ether ether)ketone (SPEEK)-AgNO3, were prepared and tested for separation of the isoprene/n-pentane mixtures. The performances of the membranes were significantly affected by the degree of sulfonation (DS) of PEEK. The selectivity over n-pentane increased with the increasing DS of PEEK.
저자 최현우1, 강석현1, 정병만1, 안의섭1, 김동범1, 최대기1, 김훈식2, 이창하3
소속 1한국과학기술(연), 2경희대, 3연세대
키워드 separation; membrane; olefin/paraffin
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