학회 | 한국화학공학회 |
학술대회 | 2016년 봄 (04/27 ~ 04/29, 부산 BEXCO) |
권호 | 22권 1호, p.1175 |
발표분야 | 촉매 및 반응공학 |
제목 | A study on the low temperature SCR activity enhancement with the addition of tungsten of Mn-Ce-Ti catalyst |
초록 | This study is performed on the reaction characteristics of the selective catalytic reduction (SCR) using ammonia for a removal of nitrogen oxides (NOx). Mn-Ce-W-Ti catalysts were prepared by a wet impregnation method. Tungsten loadings of catalysts were 0-10 wt.%. The SCR activity is increased to the maximum when it included 5 wt.% tungsten. But it showed a tendency to decrease when tungsten added more than that. The properties of the catalyst were evaluated using H2 temperature-programmed reduction (H2-TPR) and X-ray photoelectron spectroscopy (XPS). As a result, the Mn4+ and Ce3+ peaks increased with the addition of W in H2-TPR. Also, when the tungsten 5 wt.%, the ratio of Mn4+ and Ce3+ species present the highest. Thus, The ratio of Mn4+ and Ce3+ was comfimed an important factor on the reaction of low temperature SCR. (This subject is supported by Korea Ministry of Environment (MOE) as “Advanced Technology Program for Environmental Industry”(RE201411036)) Keywords : Mn, low temperature SCR, promotor, XPS |
저자 | 김동호1, 권동욱2, 홍성창2, 남기복2, 최상현3, 박광희3, 김기왕3 |
소속 | 1경기대, 2경기대 환경에너지공학과, 3(주)에코프로 |
키워드 | 환경촉매 |
원문파일 | 초록 보기 |