학회 |
한국고분자학회 |
학술대회 |
2007년 봄 (04/12 ~ 04/13, 제주 ICC) |
권호 |
32권 1호 |
발표분야 |
고분자 합성 |
제목 |
Preparation of metal and metal oxide nanoparticles using poly(ethylene oxide -b- N- vinylimidazole) |
초록 |
PEO–based RAFT(reversible addition fragmentation chain transfer) agent was synthesized in THF by the reaction of ω-brominated poly(ethylene oxide) with potassium ethyl xanthogenate. PEO –b- PVI was successfully synthesized in toluene at 70℃ via RAFT polymerization of N-vinylimidazole using PEO-based RAFT agent and AIBN. Water-soluble PEO-based block copolymers exhibited pH sensitive solution behavior of the resulting water-soluble block copolymers was observed. Poly(ethylene oxide -b- N-vinylimidazole) was also utilized as polymeric surfactant to prepare metal nanoparticles such as silver and gold, magnetite. We were successfully prepared magnetite(Fe3O4) nanoparticles. |
저자 |
최송이1, 김경민1, 고다현1, 전희정1, 박형수2, 박건희1, 김정안1
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소속 |
1경희대, 2서강대 |
키워드 |
poly(ethylene oxide -b- N- vinylimidazole); RAFT; nanoparticle
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E-Mail |
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