화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2006년 가을 (10/27 ~ 10/28, 고려대학교)
권호 12권 2호, p.2233
발표분야 에너지/환경
제목 Anaylsis of Fixed Bed Reactor for DME Synthesis
초록 Dimethyl Ether (DME) is considered as one of the most promising candidates for the substitute of LPG and diesel fuel. We analyzed one-step DME synthesis from syngas in a shell and tube type fixed bed reactor with consideration of the heat and mass transfer between catalyst pellet and reactants gas and effectiveness factor of catalysts together with reactor cooling through reactor wall. Simulation results showed strong effects of pore diffusion. By this simulator we compared the experimental data of a pilot-scale DME reactor with simulation results such as temperature profile, CO conversion and DME productivity. Operating condition of the reactor is as follows: GHSV 2000 hr-1, feed temperature 220℃, reactor pressure 50 bar, H2 : CO ratio 1.5:1, feed temperature of cooling water 180℃. This simulator helps control the temperature of the reactor and prevent the irreversible deactivation of catalyst.
저자 송대성1, 안성준1, 조원준2, 박달근1, 윤인섭1
소속 1서울대, 2한국가스공사
키워드 Fixed bed Reactor; Modelling; Dimethyl ether; Effectiveness factor
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