| 학회 |
한국화학공학회 |
| 학술대회 |
2009년 봄 (04/23 ~ 04/24, 광주 김대중컨벤션센터) |
| 권호 |
15권 1호, p.1061 |
| 발표분야 |
촉매 및 반응공학 |
| 제목 |
Slurry-phase Fischer-Tropsch synthesis using Co/γ-Al2O3, Co/SiO2 and Co/TiO2: effect of support on catalyst aggregation |
| 초록 |
The activity of Fischer-Tropsch Synthesis (FTS) was investigated in a slurry-phase reaction with cobalt-based catalysts such as Co/γ-Al2O3, Co/SiO2 and Co/TiO2. Although Co/SiO2 catalyst showed higher CO conversion than the other catalysts, intrinsic activity is much higher on Co/TiO2 having a large pore size and cobalt particle size. Catalyst deactivation with the formation of catalyst aggregation was observed on Co/γ-Al2O3 which is characterized to show low formation rate of oxygenates. The alcohols derived FTS reaction and large pore size of catalyst possibly inhibit catalyst aggregation. Although the intrinsic activity (turn-over frequency; TOF) of cobalt-based catalyst is generally affected by cobalt particle size with different reducibility, the intrinsic activity is simultaneously affected by the average pore size of catalyst in a slurry-phase FTS reaction. |
| 저자 |
배종욱, 오종혁, 박선주, 이윤조, 전기원
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| 소속 |
한국화학(연) |
| 키워드 |
Fischer-Tropsch synthesis; turn-over frequency; pore size of catalyst; slurry-phase reaction; product distribution
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| E-Mail |
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| 원문파일 |
초록 보기 |
