화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2011년 봄 (04/07 ~ 04/08, 대전컨벤션센터)
권호 36권 1호
발표분야 분자전자용 소재 및 소자
제목 Detailed Investigation of Light Induced Charge Injection into a Single Conjugated Polymer Chain
초록 Detailed single molecule spectroscopic results are presented for the recently reported oxidation of single-chain conjugated polymers of MEH-PPV at the HTL/insulator interface of an MIS device. The charge injection process was determined to be light dominated with no charging occurring in the dark at any applied bias. The nature of the optical preparation of the injected charge is explored by a range of single molecule fluorescence voltage modulation techniques. The observed charging dynamics are highly consistent with a cooperative charging effect. It is also observed that analogous charing occurs for the conjugated polymer F8BT. The chargin/discharging dynamics were investigated indirectly by a variety of single molecule electro-optical spectroscopic techniques, including an "image-capture"approach.
저자 이광직1, Josh Bolinger2, Paul F. Barbara2
소속 1삼성전기, 2Univ. of Texas at Austin
키워드 Single molecule spectroscopy; conjugated polymer; charge injection
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