| 학회 |
한국고분자학회 |
| 학술대회 |
2014년 봄 (04/10 ~ 04/11, 대전 컨벤션센터) |
| 권호 |
39권 1호 |
| 발표분야 |
고분자구조 및 물성 |
| 제목 |
Preperation and characterization of tetraphnylene structured polymer electrolyte membrane containing grafted propane sulfonic acid |
| 초록 |
The tetraphnylene structured sulfonated poly(ether sulfone)s were synthesized by polycondesation of 4,4-(2,2-diphenylethenylidene)bisphenol (DHTPE), 4,4-hydroxyphenylsulfone and 4,4-fluorophenylsulfone and then followed by bromination and grafting with 3-bromopropane sulfonic acid potassium salt. The polymer salt form was converted to free acid using 1.0 M sulfuric acid solution. All these membranes were casted from dimethylacetamide (DMAc) solution. The structural properties of the synthesized polymers were investigated by 1H NMR spectroscopy and FT-IR. The membranes’ properties were studied by ion exchange capacity (IEC), thermogravimetric analysis (TGA), water uptake, and also proton conductivity assessment. Membrane’s chemical stability was investigated by Fenton test. |
| 저자 |
임진성, 이순호, 이상영, 주현호, 진레이, 김환기
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| 소속 |
건국대 |
| 키워드 |
grafting polymer; bromine; Dimensional stability; Fenton’s reagent
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| E-Mail |
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