화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2019년 가을 (10/09 ~ 10/11, 제주컨벤션센터)
권호 44권 2호
발표분야 고분자구조 및 물성
제목 Controlling Cubicity of PS-b-PMMA Double Gyroid Unit Cell in the Direction Perpendicular to the Substrate: Inducing Reflection Wavelength Difference
초록 In this study, we present a facile approach to control cubicity of double gyroid (GYR) unit cell in the direction perpendicular to the substrate using polystyrene-b-poly(methyl methacrylate) (PS-b-PMMA) self-assembly. Evaporation-control solvent vapor annealing (ECSVA) was used to control cubicity without any deformation of the structure in lateral direction. PS-b-PMMA GYR with two different cubicity parameter obtained from the ECSVA were transformed to Air-Al2O3 GYR through sequential infiltration synthesis and following treatment with O2 plasma to enhance refractive contrast between the channel and matrix of GYR. With successfully increased refractive contrast which sharpens UV reflectance peak to observe photonics-related property more effectively, GYR having different cubicity exhibits difference in reflection wavelength owing to dimensional contrast of the unit cell in the direction perpendicular to the substrate.
저자 조승연1, 정현수2, 전태석1, 박성민3, 이우섭1, 서승기1, 김형준1, 김광진4, 이승우4, 류두열1
소속 1연세대, 2LG 화학, 3RPI, 4고려대
키워드 Cubicity; PS-b-PMMA; Double Gyroid Unit Cell; Reflection Wavelength Difference
E-Mail