| 학회 |
한국고분자학회 |
| 학술대회 |
2009년 가을 (10/08 ~ 10/09, 광주과학기술원 오룡관) |
| 권호 |
34권 2호 |
| 발표분야 |
고분자 합성 |
| 제목 |
Electro-optical and Electrochemical Properties ofa Conjugated Cyclopolymer Prepared by the Ring-Forming Polymerization of a-Methyldipropargylamine |
| 초록 |
A new conjugated cyclopolymer, poly(α-methylbenzyl dipropargylamine), was prepared by the ring-forming polymerization of α-methylbenzyl dipropargylamine in high yields. The cyclovoltamograms of the polymer exhibited the irreversible electrochemical behaviors between the doping and undoping peaks. It was found that the kinetics of the redox process of poly(MBDPA) might be mainly controlled by the electron transfer process from the experiment of the oxidation current density of poly(MBDPA) versus the scan rate. The photoluminescence peaks of poly(α-methylbenzyl dipropargylamine) was observed at 443 nm corresponding to the photon energy of 2.80 eV. |
| 저자 |
제갈영순1, 이원철1, 진성호2, 박종욱3, 류원석4, 김상율5
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| 소속 |
1경일대, 2부산대, 3가톨릭대, 4영남대, 5한국과학기술원 |
| 키워드 |
Conjugated Polymer; Cyclopolymerization; PL; CV; TGA
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| E-Mail |
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