화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2010년 가을 (10/07 ~ 10/08, 대구 EXCO)
권호 35권 2호
발표분야 분자전자소재 및 소자
제목 Electrical Memory Characteristics of a Non-Doped p-Conjugated Polymer Bearing Carbazole Moieties
초록 Poly[bis(9H-carbazole-9-ethyl)dipropargylmalonate] (PCzDPM) is a novel p-conjugated polymer bearing carbazole moieties that has been synthesized by the polymerization of bis(9H-carbazole-9-ethyl)dipropargylmalonate with the aid of molybdenum chloride solution as the catalyst. The charge-transport characteristics of PCzDPM in nanometer-scaled thin films were studied as functions of temperature and film thickness. PCzDPM films with a thickness of 1530 nm were found to exhibit very stable dynamic random access memory (DRAM) characteristics without polarity. Furthermore, the polymer films retain DRAM characteristics up to 180°C. The ON-state current is dominated by Ohmic conduction and the OFF-state current appears to undergo a transition from Ohmic to space charge limited conduction with a shallow-trap distribution. The ON/OFF switching of the devices is mainly governed by filament formation.
저자 박삼대1, 이택준2, 김진철1, 김동민1, 김경태1, 권원상1, 고용기1, 최흥열1, 장태현1, 이문호1
소속 1포항공과대, 2삼성전자
키워드 conjugate polymer; carbazole moiety; volatile polymer memory; dynamic random access memory; electrical ON/OFF switching; switching mechanism
E-Mail