화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2008년 봄 (04/10 ~ 04/11, 컨벤션 뷰로(대전))
권호 33권 1호
발표분야 나노카본/고분자 복합소재의 제조 및 응용기술
제목 Deposition of Pt-Ru nanoparticles on the conductive polymer -coated MWNT by various reduction techniques for DMFC
초록 Carbon nanotubes (CNT) exhibit extraordinary mechanical, thermal, and electrical properties due to their unique one-dimensional all-carbon structure. In this study, polypyrrole, polythiophene, poly(3-thiopheneacetic acid), and polyaniline with hydrophilic property was coated on the surface of MWNT, respectively, by in-situ polymerization. Subsequently, Pt-Ru alloy nanoparticles were deposited on the polypyrrole, polythiophene, poly(3-thiopheneacetic acid), and polyaniline-coated MWNT by chemical reduction assisted with microwave and ultrasonic irradiation, respectively. The catalytic efficiency of Pt-Ru@polymer/MWNT catalysts was determined to MeOH oxidation and CO adsorption ability. The catalytic efficiency of Pt-Ru@PPy/MWNT catalyst prepared by chemical reduction assisted with ultrasonic irradiation for MeOH oxidation is higher than that of the other catalysts.
저자 양대수1, 명교림2, 전종한2, 최성호1
소속 1한남대, 2한밭대
키워드 the conductive polymer; DMFC; MWNT
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