화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2018년 봄 (05/02 ~ 05/04, 대구 엑스코(EXCO))
권호 22권 1호
발표분야 에너지저장변환_포스터
제목 Enhanced Electron Diffusion Length and Correcting efficiency in the photo anode containing Mo-doped TiO2 blocking Layers in DSSCs
초록 The power conversion efficiency of dye-sensitized solar cells has been limited because electron transport is not fully achieved, and the injected electrons always recombine with the acceptor species before the electrode can collect them. The concept of introducing metal-doped TiO2 blocking layer into the mesoporous TiO2 network of dye-sensitized solar cells is proposed to enhance the power conversion efficiency. DSSCs based on Mo-TiO2 blocking layer show an advantage in increasing he charge transport. The charge transfer resistance in DSSC is significantly suppressed by the Mo-doping. As a result of the downward shifted conduction band and increased charge transport, the photocurrent density of the device is improved remarkably with an almost unchanged photovoltage. The highest power conversion efficiency (η = 8.03%) is obtained at 4% Mo-doping, which shows increases by 13% in Jsc and by 7% in η, as compared with the undoped DSSC.
저자 김동우1, 전지훈1, Suresh Thogiti1, Ganesh Koyyada1, 이도경2, 김재홍1
소속 1영남대, 2대구가톨릭대
키워드 Electron Diffusion; Mo-doped; blocking Layers; DSSCs
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