화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2003년 가을 (10/10 ~ 10/11, 부경대학교)
권호 28권 2호, p.57
발표분야 고분자 구조 및 물성
제목 Alignment of Oligofluorenes on PEDOT/PSS Conducting Polymer
초록 Strong alignment of the hepta-oligofluorene with 2-ethylhexyl side branches was achieved upon annealing in the liquid crystalline state on the rubbed surface of PEDOT/PSS conducting polymer. We employed near edge x-ray absorption fine structure spectroscopy (NEXAFS) to investigate the degree of molecular orientation at the top surfaces of the oligofluorene and the PEDOT/PSS layers. Our results show a slight segmental orientation on the rubbed PEDOT/PSS surface but a very high molecular orientation on the oligofluorene surface. The mechanism responsible for this surprising alignment behavior will be discussed.
저자 정영석1, 조정호1, J. Luening2, P. Theato1, C. Frank3, 윤도영1
소속 1서울대, 2Stanford Synchrotron Radiation Laboratory, 3Chemical Engineering Department of Stanford Univ.
키워드 nexafs; pedot; oligofluorene
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