| 학회 |
한국고분자학회 |
| 학술대회 |
2010년 봄 (04/08 ~ 04/09, 대전컨벤션센터) |
| 권호 |
35권 1호 |
| 발표분야 |
기능성 고분자 |
| 제목 |
Self-doping Polypyrrole Nanocomposites Electrochemistry and Structure of the Self-doped System |
| 초록 |
A novel class of self-doping conjugated polymer, polystyrene-polypyrrole (PSt-PPy) core-shell nanoparticles were successfully prepared via Fe3+-catalyzed oxidative and emulsifier-free emulsion polymerization. To induce conductivity of the PSt-PPy core-shell nanoparticles, modified two-stage shot-growth method was introduced. Core-shell structure of the resulting nanoparticles were proved by SEM and TEM. The resulting self-doped conducting core-shell nanoparticles showed conductivity from 0.15 S/cm to 0.2 S/cm after two-stage shot-growth method. The surface compositions and doping level of the self-doped conducting core-shell PSt-PPy nanoparticles were examined by X-ray photoelectron spectroscopy (XPS). Calculated the doping level of the self-doped conducting core-shell PSt-PPy) nanoparticles is 28% by using N+ and N atoms area. |
| 저자 |
조연화1, 이승모1, 이선종1, 이준영2, 정인우3, 류두열1, 김중현1
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| 소속 |
1연세대, 2한국생산기술(연), 3경북대 |
| 키워드 |
Conducting polymer; Polypyrrole; Core-shell; Two-stage Shot-growth Method
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| E-Mail |
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