| 학회 |
한국고분자학회 |
| 학술대회 |
2016년 봄 (04/06 ~ 04/08, 대전컨벤션센터) |
| 권호 |
41권 1호 |
| 발표분야 |
분자전자 부문위원회 I |
| 제목 |
Effect of Thiophene and Selenophene Moiety in Regular Terpolymers on the Performance of Thin Film Transistors and Polymer Solar Cells |
| 초록 |
The three different terpolymers such as PDPP-TTS, PDPP-TSS, and PDPP-TTSS composed of thiophene and selenophene derivatives cotrolling the conjugation length of repeating unit and the composition ratio of donor moieties were newly designed for the study of the structure-property relationship. This approach makes the three materials to display different optical absorption and electrochemical properties. Interestingly, PDPP-TTSS containing bithiophene (TT) and biselenophene (SS) have edge-on chain orientation which is similar to the copolymers of PDPP-TT containing bithiophene and PDPP-SS bearing biselenophene only while PDPP-TTS and PDPP-TSS showed mixed orientations in face-on and edge-on manners. The device showed the power conversion efficiency (PCEs) of PDPP-TSS and PDPP-TTSS have 4.18 % and 4.76% respectively which indicates that the properties of regular terpolymers were markedly enhanced by inserting the thiophene moiety into the donor part of the DPP-based terpolymer, PDPDP-SS. |
| 저자 |
이지형, 박지은, 최수나, 이대희, 엄현아, 조민주, 최동훈
|
| 소속 |
고려대 |
| 키워드 |
terpolymer; mixed orientation; conjugation length
|
| E-Mail |
|
