화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2005년 가을 (10/28 ~ 10/29, 건국대학교)
권호 9권 2호
발표분야 촉매
제목 Catalytic Removal of NO over Molybdenum Nitrides
초록 The catalytic NO removal reactions were investigated using a series of Mo nitrides. Mo nitrides were synthesized using Mo oxide (MoO3) and ammonia gas (NH3) with different heating rates and space velocity. Various characterization techniques such as BET surface area and oxygen uptake measurements were employed to characterize different Mo nitrides synthesized in this study. Depending on the preparative conditions, BET surface areas ranged from 1 m2/gr to 28 m2/gr and oxygen uptake values varied from 0.46 ㎛ol/g to 5.41 ㎛ol/g. The Mo nitrides were found to be active for NO removal reactions. Although some Mo nitrides catalysts were exceeded by Pt/Al2O3 catalyst, the steady state reaction activities of other Mo nitrides catalysts were comparable to or even higher than that of the Pt/Al2O3 catalyst. These results implied that Mo nitrides could be one of the promising catalysts that might be able to replace platinum group noble metal catalysts in the NO removal reactions.
저자 이대수, 최정길, 김극태
소속 한남대
키워드 Catalytic; Molybdenum; Nitrides
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