화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2011년 가을 (10/06 ~ 10/07, 김대중 컨벤션센터)
권호 36권 2호
발표분야 고분자가공/복합재료-나노카본 고분자 복합필름
제목 Change of Miscibility Window of PC and PMMA by Adding Multiwall Carbon Nanotubes
초록 The alloys of polycarbonate (PC) and poly(methyl methacrylate) (PMMA) are the typical model system in which a lower critical solution temperature (LCST) behavior appears. We employed Flory-Huggins theory to investigate the change of miscibility window by adding small amount of carbon nanotubes into the alloy. We calculate binodal and spinodal phase separation curve by F-H theory. The cloud points are consistent with the spinodal phase separation curve rather than the binodal curve. We demonstrated the phase behavior of PC-PMMA blends are changed by adding a small amount of multiwall carbon nanotube. The change of F-H interaction parameter between PC and PMMA by adding MWCNT was evaluated.
저자 배도영1, 유승찬2, 오석빈2, 이헌상1
소속 1동아대, 2삼양사 신소재(연)
키워드 Polycarbonate; PC; Poly (methyl methacrylate); PMMA; LCST; CNT
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