| 학회 | 한국화학공학회 |
| 학술대회 | 2011년 봄 (04/27 ~ 04/29, 창원컨벤션센터) |
| 권호 | 17권 1호, p.635 |
| 발표분야 | 열역학 |
| 제목 | The Measurements of Carbon Dioxide Hydrate Equilbrium in Water and Methanol Solutions |
| 초록 | Carbon dioxide hydrate phase equilibrium involving inhibitor is important for the flow assurance in the transmission lines. Of the inhibitors, methanol is used the most frequently for its high volatility. In this study three-phase (Lw-H-Lg) equilibria for mixtures of carbon dioxide, water and methanol were experimentally studied for P=(5 to 20) MPa. Isobaric dissolution temperatures of formed hydrates were measured for accurately determined loading compositions of all components. Literature data for this mixture were reported with only weight fraction of methanol in the aqueous solution and are considered incomplete because the equilibrium can be sensitive to the ratio of carbon dioxide to aqueous solution. The ratio effects were verified by present data at constant weight fraction of methanol. CSMGem calculations using the program in Sloan and Koh [1] were found in general agreements with present data. [1] E.D. Sloan, C.A. Koh, Clathrate hydrates of natural gases, 3rd ed., CRC Press, Boca Raton, FL, 2008. |
| 저자 | 김선형, 강정원 |
| 소속 | 고려대 |
| 키워드 | hydrate; inhibitor; carbon dioxide; methanol |
| 원문파일 | 초록 보기 |
