| 학회 | 한국공업화학회 |
| 학술대회 | 2017년 가을 (11/08 ~ 11/10, 부산 벡스코(BEXCO)) |
| 권호 | 21권 2호 |
| 발표분야 | 정밀화학_포스터 |
| 제목 | Synthesis of polynitropyrazole derivatives via nitrodeiodination |
| 초록 | Polynitropyrazoles have been extensively studied for their high thermal stability, insensitivity and excellent explosive performance. 3,4,5-trinitropyrazole (TNP) and 2,4,5-trinitroimidazole (TNI) are representative azole-based molecular explosives. Many synthetic methods for introducing nitro groups have been reported. Nitrodeiodination is an efficient method which can introduce nitro groups into the structure with iodine introduced. Herein, we will introduce experimental results for introducing nitro groups into polyiodopyrazoles via nitrodeiodination. Our group synthesized polynitropyrazole derivatives as precursors of HEMs through the nitrodeiodination reaction of polyiodopyrazoles. |
| 저자 | 김남태, 이윤재, 김한울, 김영규 |
| 소속 | 서울대 |
| 키워드 | pyrazoles; nitrodeiodination; High energy materials(HEMs) |
