화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2019년 봄 (04/10 ~ 04/12, 부산컨벤션센터(BEXCO))
권호 44권 1호
발표분야 고분자가공/복합재료
제목 Enhanced Photoluminescence via Integration of Block copolymer-Quantum dots
초록 Achieving high efficiency in quantum dots (QDs) films is essential for the low energy consumption which is the requirement for the next-generation display and lighting. Despite many efforts in developing high quantum yield (QY) in solution state, most QD films in actual devices have suffered from low excitation of QDs, poor light extraction and non-radiative energy transfer between adjacent QDs, deteriorating the photoluminescence (PL) QY. Herein, we suggest a facile strategy through the fabrication of QD-BCP (poly(styrene-b-4-vinylpyridine)) film that offers the solution for all the constraints. Highly interconnected structure of the BCP facilitates the random scattering of light, leading to the enhancement of absorption and extraction, respectively. Additionally, the nanometer-scales phase separation of two blocks with the conjugation effects enables the dispersion of QDs in the matrix, hence reducing the non-radiative energy transfer.
저자 김건영, 정연식
소속 한국과학기술원
키워드 Block copolymers; Quantum dots; Vapor-induced phase separation; Porous structure; Spinodal decomposition; Light scattering; Enhanced light absorption; Enhanced light extraction
E-Mail