화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2015년 가을 (11/04 ~ 11/06, 제주국제컨벤션센터(ICCJEJU))
권호 19권 2호
발표분야 환경에너지_포스터
제목 CATALYTIC HYDRODEOXYGENATION OF A MODEL COMPOUND IN PYROLYSIS BIO-OIL OF SACCHARINA JAPONICA
초록 The model compound of 2-furyl methyl ketone (2-FMK) a product of pyrolysis oil from Saccharina japonnica was used for hydrodeoxygenation (HDO) using spray-pyrolysis (S.P) prepared catalysts (Ni, Co and CoP) and incipient-wetness impregnation (I.W) prepared catalysts (Ni), supported on γ-Al2O3. The effect of catalyst activity and stability on 2-FMK at different reaction temperatures and calcination temperatures were investigated. Catalyst activity increased with increase in calcination temperature, but decreased with increase in reaction time, for all catalysts. The spray-pyrolysis prepared catalyst Ni/γ-Al2O3-S.P (Ni-loading of 10 wt%, calcinated at 800 ℃) showed the best activity with 83.02% in 2-FMK conversion at 400 ℃. The produced gas and liquid was analyzed by gas chromatography (GC) with TCD/FID detector and GC-MS, respectively, to determine the product compositions.
저자 우희철1, 김진수2, 김승수3, 고영채2, EMMANUEL GALIWANGO3, Ly Hoang Vu2
소속 1부경대, 2Kyung Hee Univ., 3강원대
키워드 2-Furyl methyl ketone; spay pyrolysis; HDO
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