| 학회 |
한국공업화학회 |
| 학술대회 |
2017년 봄 (05/10 ~ 05/12, 광주 김대중컨벤센센터(Kimdaejung Convention Center)) |
| 권호 |
21권 1호 |
| 발표분야 |
고분자 |
| 제목 |
Covalent Organic Framework with tertiary amine gorups for Efficient SO2 Capture with High Reversibility |
| 초록 |
We successfully synthesized new series of imide-linked COFs that incorporates DMMA as the modulator via a microwave-assisted reaction. The surface-functionalized channel of imide-linked COF for the interaction with SO2 was achieved through the dimethyl amine functional groups of DMMA. In addition, well-defined large surface areas could afford the channels that can pass SO2 gas through. These imide-based COFs utilizing SO2 and tertiary amine-reversible interactions could be perfectly recovered in a recycling process. Substituted as 10% of the functional group, the molar SO2 sorption capacity was recorded up to 6.30 mmol SO2 g-1 (40 wt%). Furthermore, we found that functionalized PI-COF-m10 was completely reversible for SO2 and highly stable on repeated sorption–desorption cycles. The slightly disturbed crystal structure with 10% tertiary amine functionalization in PI-COF-m10 could accomplish both outstanding SO2 capacity and the high reproducibility. |
| 저자 |
임채성1, 박태호1, 이강영2
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| 소속 |
1포항공과대, 2한국건설생활환경시험(연) |
| 키워드 |
SO2 capturing; recycling; enviroment
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| E-Mail |
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