화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2016년 가을 (10/26 ~ 10/28, 제주국제컨벤션센터(ICCJEJU))
권호 20권 2호
발표분야 환경에너지_포스터
제목 Effective analysis of cations and anions in spent desulfurized waste for the preparation of NaHCO3: A titration study with interfering ions
초록 Abundant flue gases from the steel or power plant emissions should be removed before emitting to the environment. A dry fluid NaHCO3 method is a present efficient process for the desulfurization of SOx. Tons of spent waste produced every day during desulfurization of SOx similar to the production rate. Instead of dumping, the spent waste can be regenerated to avoid ground pollution. The key step in regeneration of spent waste is analysis of salts present. In this present investigation, after filtration of desulfurized spent waste, the Na2SO4, Na2CO3, and NaHCO3 were analyzed in presence of potential interferences. First cationic interference such as NH4+ was checked in determination of Na+ by sodium sensor electrode. In determination of SO42- ion, anionic interferences like HCO3- and CO32- were performed by HACH method. The limit of interference ions was derived through the calibration plot to find out the error levels of ions.
저자 이보열, 문일식
소속 순천대
키워드 Desulfurized waste; interference; Na2SO4; Na2CO3; and NaHCO3
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