화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2017년 가을 (11/08 ~ 11/10, 부산 벡스코(BEXCO))
권호 21권 2호
발표분야 콜로이드계면화학_포스터
제목 Synthesis of chalcogenide nanoparticlesat room temperature exploiting the Kirkendall effect
초록 The electrolysis of water recently attracts attention because hydrogen can be easily produced under eco-friendly conditions. The noble metal catalysts have excellent catalytic properties for the electrolysis of water, however, their high cost remains a huddle. For these reasons, cheap and good active transition metal catalysts have been widely explored. Chalcogenide has a high applicability as a catalyst, although it has to be synthesized at extreme conditions. In this study, we fabricated core-cell nanoparticles composed of NiSe or CoSe shell layer with amorphous sellenium (α-Se) core through the Kirkendall effect. The core-shell structure was examined using SEM and EDX and further electrochemical analysis was performed to verify catalytic electrolysis of water. Uniform core-shell nanoparticles with NiSe or CoSe layers were prepared at room temperature and atmospheric condition, These charcogenide nanoparticles could be applied as an electrolysis catalyst.
저자 임영준, 이상엽
소속 연세대
키워드 kirkendall effect; water splitting; chalcogenide
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