| 학회 |
한국공업화학회 |
| 학술대회 |
2021년 가을 (11/03 ~ 11/05, 대구 엑스코(EXCO)) |
| 권호 |
25권 2호 |
| 발표분야 |
포스터-전기화학 |
| 제목 |
New strategy for partial oxidation of methane via in situ H2O2 generation |
| 초록 |
Since methane is the main component of natural gas, partial methane oxidation has been widely studied as a promising route for chemical fuel synthesis. However partial oxidation of methane is a challenging process due to molecular inertness of methane (high C-H bond dissociation energy and low polarity) against activation or over-oxidation to CO2. Here we propose new methane oxidation system applying electrochemical oxygen reduction reaction (ORR). In this system in situ generated H2O2 via ORR activated CH4 and 10 μmol•h-1 of HCOOH(formic acid) was generated under ambient temperature and pressure (70 °C and 1 bar). Furthermore consecutive partial methane oxidation was successfully conducted for 12 hours. |
| 저자 |
김지원1, 오형석2, 박종혁1, 황윤정3
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| 소속 |
1연세대, 2한국과학기술(연), 3서울대 |
| 키워드 |
Partial methane oxidation; Oxygen reduction reaction; C1 chemistry
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| E-Mail |
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