화학공학소재연구정보센터
학회 한국재료학회
학술대회 2021년 가을 (11/24 ~ 11/26, 경주 라한호텔)
권호 27권 2호
발표분야 C. 에너지 재료 분과
제목 LiFePO4-Li3V2(PO4)3 nanocomposite cathode with a high energy density using one-pot Combustion synthesis
초록 Highly crystalline carbon-coated 0.66LiFePO4•0.33Li3V2(PO4)3(LFP-LVP) nanocomposite was synthesized by a one-pot combustion strategy by a polyol medium at low temperature. In this study, electron microscopy delivered the as-synthesized composite consisting of spherical particles which have average diameters in the range of 30–60nm. Following calcination, a crystal growth phenomenon and particle aggregation were observed at 800 °C, thus resulting in an increase in the average particle size to 200– 300 nm. Testing for a lithium-ion battery, the nanocomposite electrode provided good electrochemical properties with higher operating potentials hence enhanced energy density and excellent rate capacity. Corresponding to an energy density of 46.88 Wh Kg−1 at 6.4 C, the composite cathode showed a high reversible capacity of 156 mAh g−1 at 0.1 C and exhibited a remarkable reversible capacity of 119 mAh g−1.
저자 Jimin Park, Moonsu Song, Seulgi Lee, Hyeona Park, Junji Piao, Vinod Mathew, Jang-Yeon Hwang, Jaekook Kim
소속 Chonnam National Univ.
키워드 Lithium Secondary Battery
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