| 학회 |
한국공업화학회 |
| 학술대회 |
2016년 봄 (05/02 ~ 05/04, 여수 엑스포 컨벤션) |
| 권호 |
20권 1호 |
| 발표분야 |
촉매_포스터 |
| 제목 |
The Effect of Selenium Oxide on Palladium-Catalyzed Reductive Carbonylation of Nitrobenzene to Methyl N-phenyl carbamate |
| 초록 |
Selenium compounds have been reported as a highly effective catalytic system in oxidative carbonylation of aromatic amines to corresponding carbamates and ureas. The present study reveals more about the selectively-promoting-effect of selenium oxide on Palladium- catalyzed reductive carbonylation of nitrobenzene to produce methyl N-phenyl carbamate with high yield of carbamate (~90%) and high selectivity (~90%) in the presence of pyridine as co-catalyst. |
| 저자 |
Huynh Nguyen Thuy Tram1, Thanh Tung Nguyen1, Anh Vy Tran1, 김용진2
|
| 소속 |
1UST, 2한국생산기술(연) |
| 키워드 |
Carbon monoxide. SeO2. Selenium oxide. Reductive carbonylation; Nitrobenzene; Carbamate; Non-phosgene
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| E-Mail |
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