학회 |
한국고분자학회 |
학술대회 |
2015년 가을 (10/06 ~ 10/08, 대구컨벤션센터(EXCO)) |
권호 |
40권 2호 |
발표분야 |
기능성 고분자 |
제목 |
Polymer electrolyte with polyurethane (PU)-polyaniline (PANi) supramolecular network structure |
초록 |
Poly (2-aminobenzyl alcohol) (PAA) was prepared by chemical oxidative polymerization in the presence of sulfonated polystyrene microspheres as template and hydrochloric acid as dopant. Polyurethane (PU)-PAA supramolecular network was synthesized using urethane reaction of polyethylene glycol (PEG) and MDI-terminated PAA microsphere. The chemical bonding of PU-PAA structure was confirmed by comparing the FT-IR spectrum of the pure PAA polymer and crosslinked PU–PAA copolymer. The morphological and optical change of PU-PAA supramolecular network as functions as pH and Li+ concentration was investigated by scanning electron microscopic (SEM) and UV–vis–NIR absorption spectroscopy. The ionic conductivities of PU-PAA/Li+ complexes at a fixed pH was also evaluated through impedance analysis. |
저자 |
허필호, 김지현
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소속 |
부산대 |
키워드 |
sphere; beads; conducting polymer
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E-Mail |
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