화학공학소재연구정보센터
학회 한국재료학회
학술대회 2014년 가을 (11/27 ~ 11/28, 대전컨벤션센터)
권호 20권 2호
발표분야 A. 전자/반도체 재료(Electronic and Semiconductor Materials)
제목 Kinetics of Ni/Ta-interlayer/Ge Reactions Studied by in-situ Transmission Electron Microscopy
초록 This study examined the reaction kinetics for the growth of Ni germanide in the Ni/Ge and the Ni/Ta-interlayer/Ge systems using isothermal in situ annealing in TEM. The reaction in the Ni/Ge system was determined to be diffusion controlled with an activation energy of 0.92 ± 0.19 eV. In addition, the growth rate of Ni germanide in the Ni/Ta-interlayer/Ge system was also diffusion limited and depended on the square root of the time with activation energy of 1.13 ± 0.10 eV. For the Ni/Ta-interlayer/Ge system, the reason for the increase in activation energy was due to the combination of the Ta-rich layer and the ternary amorphous layer formed in the initial stage of the annealing process.
저자 Jae-Wook Lee, Jee-Hwan Bae, Tae-Hoon Kim, Hyoungsub Kim, Cheol-Woong Yang
소속 Sungkyunkwan Univ.
키워드 kinetics; Ni germanide; isothermal annealing; in-situ TEM
E-Mail