화학공학소재연구정보센터
학회 한국재료학회
학술대회 2012년 봄 (05/17 ~ 05/18, 무주덕유산리조트)
권호 18권 1호
발표분야 F. 광기능/디스플레이 재료(Optical Functional and Display Materials)
제목 Effect of Au-ionic Doping Treatment on SWNT Flexible Transparent Conducting Films
초록 Interest in flexible transparent conducting films (TCFs) has been growing recently mainly due to the demand for electrodes incorporated in flexible or wearable displays in the future.  
Indium tin oxide (ITO) thin films, which have been traditionally used as the TCFs, have a serious obstacle in TCFs applications. SWNTs are the most appropriate materials for conductive films for displays due to their excellent high mechanical strength and electrical conductivity. In this work, the fabrication by the spraying process of transparent SWNT films and reduction of its sheet resistance on PET substrates is researched  
Arc-discharge SWNTs were dispersed in deionized water by adding sodium dodecyl sulfate (SDS) as surfactant and sonicated, followed by the centrifugation. The dispersed SWNT was spray-coated on PET substrate and dried on a hotplate. When the spray process was terminated, the TCF was immersed into deionized water to remove the surfactant and then it was dried on hotplate. The TCF film was then was doped with Au-ionic doping treatment, rinsed with deionized water and dried. The surface morphology of TCF was characterized by field emission scanning electron microscopy. The sheet resistance and optical transmission properties of the TCF were measured with a four-point probe method and a UV-visible spectrometry, respectively. This was confirmed and discussed on the XPS and UPS studies.
We show that 87 Ω/□ sheet resistances with 81% transmittance at the wavelength of 550nm. The changes in electrical and optical conductivity of SWNT film before and after Au-ionic doping treatments were discussed. The effect of Au-ion treatment on the electronic structure change of SWNT films was investigated by Raman and XPS.
저자 민형섭1, 정명선1, 최원국1, 김상식2, 이전국1
소속 1한국과학기술(연), 2고려대
키워드 Transparent Conducting Films (TCF); Single-well Carbon Nanotubes (SWNT); Spray coating; Au-ionic treatment
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