학회 |
한국고분자학회 |
학술대회 |
2019년 가을 (10/09 ~ 10/11, 제주컨벤션센터) |
권호 |
44권 2호 |
발표분야 |
분자전자 부문위원회 II |
제목 |
Achieving over 5.0% Efficiency in Single-component Polymer Solar Cells Derived from a Fully Conjugated Block Copolymer Synthesized via One-pot Polymerization |
초록 |
Conjugated block copolymers containing donor (D) and acceptor (A) blocks have high potential for single component polymer solar cells (SC-PSCs), but still exhibit the difficulty of polymer synthesis and low device efficiency. In this research, a new fully conjugated D-A block copolymer (CDABP) was successfully synthesized through one-pot polymerization. The CDABP contains PBDT2T of p–type units and PNDI-Se of n–type blocks along the polymer chains. The single component polymer solar cell (SC-PSC) with a CDABP film showed the maximum power conversion efficiency (PCE) of 5.30% which is much higher than that (2.62%) of the device with the as-cast film. This perform can be attributed to its fine internal/surface morphology and high crystallinity of CDABP film. |
저자 |
김지현, 박수홍, 권나연, 조민주, 최동훈
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소속 |
고려대 |
키워드 |
Single component solar cell; Solution process
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E-Mail |
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