초록 |
CaCO3absorbed sodium dodecyl benzene sulfonate surfactant was prepared. Core-shell polymers of functional monomer inorganic/organic pair, which have both core and shell component, were synthesized by sequential emulsion polymerization using methyl methacrylate,ethyl acrylate,butyl acrylate,styrene as a shell monomer and ammonium persulfate as an initiator and 2-ethylhexyl acylate as functional monomer was obtained. We found that when core prepared by adding SDBS, MMA, EA, BA, St shell polymerization was carried out on the surface of CaCO3 particle without forming the new MMA particle during MMA shell polymerization in the core-shell polymer preparation. |