| 학회 | 한국공업화학회 |
| 학술대회 | 2015년 가을 (11/04 ~ 11/06, 제주국제컨벤션센터(ICCJEJU)) |
| 권호 | 19권 2호 |
| 발표분야 | 정밀화학_포스터 |
| 제목 | Iodine-rich compounds of pyazole-based structure |
| 초록 | Agent Defeat Wapons (ADWs) has been developed to minimize collateral damage occurred from chemical and biological weapons by deactivating biological agents with hydroiodic acid (HI) and iodine (I2). For this reason, iodine-rich compounds, such as 3,4,5-triiodopyrazole and Tris(3,4,5-triiodopyrazolyl)-2,4,6-triazine, have been designed as ADWs candidates. Among the previously designed ADWs candidates, pyrazole derivatives have been interesting to us not only because of the simple structure of pyrazole, but also because of its high stability and strong detonation property toward biocides. In this study, two bis-pyrazole compounds, bis(2,4,5-triiodo-1H-imidazol-1-yl)methane and bis(2,4,5-triiodo-1H-imidazol-1-yl)ethane, have been synthesized from 3,4,5-triiodopyrazole in 56% and 55%, resepectively, via the simple coupling reaction with diiodomethane or dibromoethane. The synthesized compounds are expected as more powerful ADWs candidates based on its increased iodine contents and symmetricity. Moreover, the symmetrical stable polyiodo-pyrazoles could be utilized as the key intermediates for high energy materials via further deiodonitration. |
| 저자 | 김영규1, 김진석2, 김남태1, 이병일1, 오정환1 |
| 소속 | 1서울대, 2국방과학(연) |
| 키워드 | ADWs; pyrazole; coupling reaction |
