| 학회 | 한국고분자학회 |
| 학술대회 | 2012년 봄 (04/12 ~ 04/13, 대전컨벤션센터) |
| 권호 | 37권 1호 |
| 발표분야 | 고분자합성 |
| 제목 | Synthesis of hetero-grafted molecular brushes with high steric congestion. |
| 초록 | A novel monomer with two different initiating groups, one for ATRP and the other for ROP, was synthesized and polymerized by RAFT polymerization. Molecular brushes were synthesized by the combination of ATRP and ROP from this backbone. The crystalline PCL was synthesized by ROP from a backbone followed by the synthesis of amorphous PBA segments by ATRP, which yielded the hetero-grafted brushes with high steric congestion. These brushes were characterized by 1H NMR, GPC, AFM, and SAXS. |
| 저자 | 김경빈, 이형일 |
| 소속 | 울산대 |
| 키워드 | hetero-grafted; molecular brushes |
