학회 |
한국고분자학회 |
학술대회 |
2009년 가을 (10/08 ~ 10/09, 광주과학기술원 오룡관) |
권호 |
34권 2호 |
발표분야 |
고분자 구조 및 물성 |
제목 |
Two-Length Scale Material from Diblock Copolymer : Neutron Reflection and Dynamic Secondary Ion Mass Spectrometry |
초록 |
Interest in nanoscale materials is immense in all the scientific area including polymer science because a new nanomaterial can lead to a more advanced and efficient technology in various application. Most of block copolymers have been known to exhibit a microphase separation from a disordered state to an ordered state upon cooling, which is referred to as the upper order-disorder transition (UODT), and from a disordered state to an ordered state on heating(LDOT). Here, we report a diblock copolymer systems containing microphase domains of one high-Tg and one low-Tg component, which show a characteristic LDOT but these formed a different lamellar phase at ambient temperature also due to their noticeable structure. This is the first time to report a two different length-scale material from a diblock copolymer itself, such materials are considered to be useful because different signals can be assigned to the corresponding switched structures. |
저자 |
윤동환1, 최동진1, 신관우1, 이연희2, 조준한3
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소속 |
1서강대, 2한국과학기술원, 3단국대 |
키워드 |
Diblock copolymer; Neutron reflection; Dynamic SIMS
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E-Mail |
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