| 학회 |
한국고분자학회 |
| 학술대회 |
2012년 가을 (10/11 ~ 10/12, 창원컨벤션센터) |
| 권호 |
37권 2호 |
| 발표분야 |
고분자합성 |
| 제목 |
Synthesis of Amphiphilic Star Block Copolymer Photo-catalyst by ATRP. |
| 초록 |
Photosensitive amphiphilic star block copolymers were synthesized by Cu based atom transfer radical polymerization (ATRP). For this, alkyl halide ATRP initiators were introduced to Pd-complexed porphyrin photo-catalyst (Pd-porphyrin) and polymerized with hydrophobic monomers such as styrene and n-butylacrylate (nBA) to prepare hydrophobic star polymer with Pd-porphyrin core. This were then used as a macroinitiator and polymerized with hydrophilic methacrylate with PEG substituent (EGMA) to synthesize amphiphilic star block copolymers with Pd-porphyrin core. These star block copolymers consisting of the hydrophobic PS (hard) or PnBA (soft) interiors and the hydrophilic PEGMA exteriors with Pd-porphyrin core were then examined as polymeric photo catalysts to remove environmental toxic compounds in water. |
| 저자 |
김지은1, 조계룡2, 최재우1, 최동훈1, 이상협2, 백경열1
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| 소속 |
1한국과학기술(연), 2고려대 |
| 키워드 |
star polymer; amphiphilic block copolymer
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| E-Mail |
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