| 학회 |
한국고분자학회 |
| 학술대회 |
2015년 봄 (04/08 ~ 04/10, 대전컨벤션센터) |
| 권호 |
40권 1호 |
| 발표분야 |
대학원생 구두발표 (발표15분) |
| 제목 |
Inhibiting the shuttle effect in lithium–sulfur batteries using a layer-by-layer assembled ion-permselective separator |
| 초록 |
A novel strategy for introducing ion-permselective properties in a conventional polyethylene (PE) separator to inhibit the shuttle effect of polysulfides in high-performance lithium–sulfur batteries is reported. This was accomplished by taking advantage of the pH-responsive multilayers of weak polyelectrolytes such as poly(allylamine hydrochloride) (PAH) and poly(acrylic acid) (PAA) assembled on the PE separator using layer-by-layer (LbL) assembly. It was found that the cationic permselectivity (permeability of cation/anion) of an ultrathin multilayer coated separator is highly tunable with respect to the number of bilayers and external pH, benefiting from fine tuning of the internal charge density of the multilayered films. The movement of polysulfide anions was significantly inhibited by five bilayers of PAH/PAA (ca. 98% with multilayers assembled at pH 3/3), while the movement of Li cations was preserved. |
| 저자 |
구민수, 이주경, 김용일, 이규태, 김병수
|
| 소속 |
UNIST |
| 키워드 |
layer-by-layer assembly; ion-permselectivity; Li-S battery
|
| E-Mail |
|
