화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2014년 가을 (10/06 ~ 10/08, 제주 ICC)
권호 39권 2호
발표분야 고분자합성
제목 Soluble Polyimides Containing Trifluoromethyl Groups
초록 Aromatic polyimides (PIs) are generally known as high-performance polymeric materials having excellent thermal, mechanical, and electrical properties. However, most of PIs are insoluble and infusible because of their rod-like chain conformation and strong interchain interactions. In this study, we synthesized new soluble PIs by introducing two CF3 pendent groups onto the aromatic ring of main chains. The PIs showed good solubility and good optical and thermal properties. Interestingly, these soluble polyimides showed a LCST behavior in organic solvents, while most of LCST behaviors have been observed with coil-like polymers dissolved in aqueous solution.
저자 김상율
소속 한국과학기술원
키워드 polyimides; synthesis; LCST
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