| 학회 |
한국고분자학회 |
| 학술대회 |
2012년 봄 (04/12 ~ 04/13, 대전컨벤션센터) |
| 권호 |
37권 1호 |
| 발표분야 |
고분자구조 및 물성 |
| 제목 |
Synthesis and Characterization of Poly(phenylene) based electolyte via Diels-Alder polymerization for Proton Exchange Membrane Fuel Cell |
| 초록 |
A series of sulfonated poly(phenylene)-based electrolytes were synthesized using 4,4'-(1,4-phenylene)-bis(2,3,5-triphenylcyclopenta-2,4-dienone) and 4,4'-sulfonyl-bis(ethynylbenzene) by Diels-Alder polymerization, and followed sulfonation with chlorosulfuric acid. The resulting polymer was structured by carbon-carbon and sulfonyl group in main chain, which is resulting chemically oxidative stable under water and hydrogen peroxide generating by H2/O2. The structural properties of the resulting polymers will be studied by Fourier transform infrared (FT-IR) spectroscopy, 1H NMR spectroscopy and thermogravimetric analysis (TGA). The membrane properties will be characterized by water uptake, ion exchange capacity and proton conductivity. |
| 저자 |
이현철, 임영돈, 이순호, Hossain, 모니룰, 장호현, 김환기
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| 소속 |
건국대 |
| 키워드 |
Proton exchange membrane; Diels-Alder; Sulfonation; Proton conductivity
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| E-Mail |
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