| 학회 | 한국화학공학회 |
| 학술대회 | 2011년 가을 (10/26 ~ 10/28, 송도컨벤시아) |
| 권호 | 17권 2호, p.1944 |
| 발표분야 | 촉매 |
| 제목 | Catalytic Effect of metalpromoters on Co/Al2O3 in the CO2 dry reforming with methane |
| 초록 | Carbon dioxide reforming of methane has been studied over Co/Al2O3 catalyst promoted with different metal additives(Ru, Ir, La, Ce, Zr) for improving catalysts performance and preventing coking. BET, XRD, ICP Mass, EDS and TEM were applied for sample characterization and dry reforming of methane was carried out a feed mixture consisted of CH4/CO2/N2=40/40/20 ratio. The amount of deposited carbon on used catalysts was determined after ca. 20hr of time on stream reaction at 973K with 20,000ml/gcat·hr. Different activity levels of the catalysts clearly show that the type of the promoter significantly affected the metal dispersion properties and catalytic performances of Co/Al2O3 catalysts. Co/Al2O3 catalyst of modified Ru-Zr exhibited the highest activity and stability among all thecatalysts prepared. |
| 저자 | 이지혜1, 남정광2, 안홍찬3, 정윤호2, 김성보3, 서정권2 |
| 소속 | 1Univ. of Science & Technology / 한국화학(연), 2환경자원연구센터, 3한국화학(연) |
| 키워드 | cobalt; dry reforming; methane; catalyst |
| 원문파일 | 초록 보기 |
