| 학회 |
한국화학공학회 |
| 학술대회 |
2001년 가을 (10/19 ~ 10/20, 한밭대학교) |
| 권호 |
7권 2호, p.2801 |
| 발표분야 |
촉매/반응공학 |
| 제목 |
Cu2(OH)3Cl/AC 촉매상에서 디메틸카보네이트의 기상합성 반응기구 |
| 초록 |
Mechanisms for vapor phase oxidative carbonylation over Cu-based catalyst was investigated. Oxidative carbonylation reaction of CH3OH with CO and O2 has been carried out under a pressure of 150psig at 403K over Cu2(OH)3Cl/AC catalysts. The plausible reaction scheme has been proposed on the basis of the reaction results between each two reactants and CO adsorption characteristics. CO has been found to be linearly adsorbed on Cu metal in Cu2(OH)3Cl/AC catalyst. TOF-SIMS spectra analysis and CO-TPD experiment were conducted to investigate CO adsortption properties. |
| 저자 |
한만석1, 이병권2, 안병성, 홍석인
|
| 소속 |
1한국과학기술(연), 2고려대 |
| 키워드 |
Mechanisms; Oxidative carbonylation; CO; Adsorption
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| E-Mail |
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| 원문파일 |
초록 보기 |
