| 학회 | 한국화학공학회 |
| 학술대회 | 2015년 가을 (10/21 ~ 10/23, 일산 KINTEX) |
| 권호 | 21권 2호, p.2436 |
| 발표분야 | Polymer self-assembly engineering symposium(고분자부문위원회) |
| 제목 | Phase Behavior and Thin Film Morphology of Star-shaped PS-block-PMMA Copolymers |
| 초록 | Star-shaped 18 arm poly(methyl methacrylate)-block-polystyrene copolymers ((PMMA-b-PS)18) were synthesized by using α-cyclodextrin (α-CD) as a core of the star-shape. Morphology of star-shaped block copolymers were characterized by TEM and small angle X-ray scattering. We also investigated thin film morphology of (PMMA-b-PS)18 exhibiting lamellar and PMMA cylindrical nanodomains. When a thin film was spin-coated on a substrate, vertically aligned lamellar and cylindrical nanodomains were obtained without any pre- or post-treatment. Moreover, vertical orientations are observed on versatile substrates, for instance, semiconductor (Si, SiOx), metal (Au), PS or PMMA-brushed substrate, and a flexible polymer sheet of polyethylene naphthalate (PEN). |
| 저자 | 곽종헌, 장상신, 김진곤 |
| 소속 | 포항공과대 |
| 키워드 | block copolymer; self-assembly; star-shaped arm |
| 원문파일 | 초록 보기 |
