| 학회 |
한국공업화학회 |
| 학술대회 |
2013년 봄 (05/01 ~ 05/03, ICC JEJU) |
| 권호 |
17권 1호 |
| 발표분야 |
포스터-나노 |
| 제목 |
Olefin Carrier Stability against Acetylene in Facilitated Transport Membranes |
| 초록 |
Facilitated olefin transport membranes based on Ag ions and metallic Ag nanoparticles (NPs) as an olefin carrier have been intensively investigated recently. It has been known that acetylene is present in many petrochemical feed stocks as an impurity and it may react with Ag ions to produce silver acetylide, a mechanically and thermally very sensitive compound. Therefore, the formation of silver acetylyde was checked by bubbling acetylene gas through aqueous AgNO3 solution. It was found that silver acetylide was immediately formed and precipitated. However, silver acetylide was not formed for surface-activated Ag NPs by electron acceptor such as 7,7,8,8-tetracyanoquinodimethane (TCNQ). Therefore, we concluded that surface-activated Ag NPs are more stable olefin carrier than Ag ions against acetylene. |
| 저자 |
김영래, 이정현, 최형우, 이성진, 이민성, 강용수
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| 소속 |
한양대 |
| 키워드 |
Silver acetylide; Olefin; Facilitated transport; Membrane; Acetylene; Silver nanoparticles
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| E-Mail |
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