화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2020년 가을 (10/05 ~ 10/08, 부산컨벤션센터(BEXCO))
권호 45권 1호
발표분야 고분자합성
제목 Synthesis and characterization of mechanophore for mechanical stimuli-responsive polymer
초록 Mechanophores are compound whose color changes due to chemical bond dissociation, molecular arrangement change and photonic crystal structure change due to mechanical force. It can be applied as a sensor and self-reporting material by using a characteristic that changes color in response to mechanical stimulation. Among various mechanopores, systems whose color changes due to dissociated bonds include spiropyrans, naphthopyrans and anthracene-based materials. In this study, we designed a molecular structure capable of self-reporting by designing a molecular structure whose optical properties change due to the dissociation of covalent bonds. The introduction of mechanopores into adhesives will act as a damage sensor. The molecular structure and properties of the mechanopores were characterized by NMR, UV-vis, ESR and PL, and the color change through impact test were also studied.
저자 이지은1, 가재원1, 최재학2
소속 1한국화학(연), 2충남대
키워드 mechanophore; stimuli sensor; mechanochromic material; self-reporting
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