화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2004년 봄 (04/09 ~ 04/10, 고려대학교)
권호 29권 1호, p.206
발표분야 분자전자 부문위원회
제목 Nonlinear Optical Chromophores containing Carbazole or Phenothiazine Bridge
초록 A number of researches have been made last one decade for the development of second-order nonlinear optical (NLO) materials because of their potential applications such as electro-optic modulator, photorefractive, optical memory devices, and optical frequency conversion system. Recently, we designed and synthesized novel NLO chromophores containing carbazole or phenothiazine bridge with respect of the push-pull model. The microscopic origin of the new NLO chromophore was studied by the UV-Vis absorption spectroscopy, ellipsometry, and cyclic voltammetry. The quantum mechanical properties were studied by using the semiempirical calculation and the energy-diagram for NLO chromophore was compared with the experimental results obtained with the electrochemical and spectroscopic analysis.
저자 이상규1, 김자연1, 조민주1, 김재홍1, 이승환1, 최동훈1, L. R. Dalton2
소속 1경희대, 2Department of Chemistry
키워드 Nonlinear Optical Chromophore; carbazole/phenothiazine bridge; quantum mechanical property
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