| 학회 |
한국화학공학회 |
| 학술대회 |
2020년 가을 (10/14 ~ 10/16, e-컨퍼런스) |
| 권호 |
26권 1호, p.693 |
| 발표분야 |
재료 |
| 제목 |
Characteristics of Sr0.92Y0.08Ti0.88V0.12Ni0.10O3-δ perovskite catalysts as Solid Oxide Fuel cell anode for methane dry reforming |
| 초록 |
Sr0.92Y0.08Ti0.88V0.12Ni0.10O3-δ (SYTVN) with perovskite structure was studied as an alternative anode matrial for utilizing internal dry reforming of CH4 (IDRM). The SYTVN exhibited excellent characteristics as IDRM catalysts. 10 mol.% of Ni was non-stoichiometrically doped in SYTV (Sr0.92Y0.08Ti0.88V0.12O3-δ) phase to improve the IDRM catalytic performance. The exsolution of bulk Ni phase was confirmed by XRD analysis. In H2-TPR, the reduction peak showed at 400 ℃ and confirmed the metal Ni phase. The CH4 conversion of the SYTVN showed 100% in comparison to SYTV which showed 80%. The H2 selectivity was similar property with Ni/YSZ. Moreover, the carbon formation was 0.886 % in SYTVN and 14.71 % in Ni/YSZ sample. The electrochemical properties were also investigated in impedance analysis, and IV-characteristics, to feasibility as SOFC (Solid Oxide Fuel cell) anode. |
| 저자 |
김준호, 장근영, 모수인, 박광선, 김지현, 윤정우
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| 소속 |
전남대 |
| 키워드 |
화공재료 |
| E-Mail |
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| 원문파일 |
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