화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2013년 가을 (10/30 ~ 11/01, 대전컨벤션센터)
권호 17권 2호
발표분야 포스터-콜로이드.계면화학
제목 Can Water-solubility of Cationics Be Increased by Adding Ethylene oxide?
초록 The desirable water solubilizing properties of surfactants have been generally obtained by using multiple-hydroxyl groups. In this work, novel cationic surfactants having excellent solubility in water were synthesized by adding ethylene oxide (EO). The di-hydroxyl cationic surfactants were prepared by the condensation reaction between alkyl glycidyl ether and methyl amine in the absence of any catalyst and solvent. After addition reaction of 2 mol and 5 mol of ethylene oxide, respectively, the desirable compounds were obtained by quaternization reaction with dimethyl sulfate. The structure of resulting products was elucidated by 1H NMR and FT-IR. The solubilities of the ethoxylated surfactants were measured and compared with that of a di-hydroxyl cationic surfactant.
저자 강은경1, 이성천1, 이하윤1, 박종목2, 이병민2
소속 1과학기술연합대, 2한국화학(연)
키워드 cationic surfactant; solubility; ethylene oxide; EO
E-Mail