| 학회 |
한국화학공학회 |
| 학술대회 |
2010년 봄 (04/22 ~ 04/23, 대구 EXCO) |
| 권호 |
16권 1호, p.619 |
| 발표분야 |
열역학 |
| 제목 |
High pressure phase behavior of lactate esters in supercritical carbon dioxide |
| 초록 |
Lactate esters are interesting chemicals which made from bio-source. Various industries, from the fine chemical industry to pharmacy, use them for the solvent, ingredient, and additive. However, Some parts of them have a difficulty of general separation process due to chemical characters of lactate esters. The problem can be solved with SCF extraction. To design and operate SCF extraction for removing lactate ester from products, high pressure phase behavior data are needed. High pressure phase behavior of methyl lactate, ethyl lactate, propyl lactate, and n-butyl lactate in CO2 is measured from 363.2 K to 323.2 K with variable volume view cell. The correlation is performed with Peng-Robinson Equation of state (PR-EOS). The critical constants and the acentric factor for PR-EOS are estimated by Constantinou /Gani method. |
| 저자 |
조동우1, 신정인1, 배 원2, 신문삼3, 권정민1, 김화용1
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| 소속 |
1서울대, 2미원스페셜티케미칼(주), 3청운대 |
| 키워드 |
Phase behavior; lactate ester; variable volume view cell; CO2
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| E-Mail |
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| 원문파일 |
초록 보기 |
